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Berkeley International is a
specialist in sourcing products worldwide. |
Our specialist for
Calcium Carbonate
is John
Eyton
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What is Calcium Carbonate? |
Calcium carbonate, or CaCO3, comprises more than 4% of
the earth’s crust and is found throughout the world. Its
most common natural forms are chalk, limestone, and
marble, produced by the sedimentation of the shells of
small fossilized snails, shellfish, and coral over
millions of years. Although all three forms are
identical in chemical terms, they differ in many other
respects, including purity, whiteness, thickness and
homogeneity. Calcium carbonate is one of the most useful
and versatile materials known to man.
Many of us encounter calcium carbonate for the first
time in the school classroom, where we use blackboard
chalk. Chalk has been used as a writing tool for over
10,000 years and is a fine, microcrystalline material.
As limestone, calcium carbonate is a biogenic rock, and
is more compacted than chalk. As marble, calcium
carbonate is a coarse-crystalline, metamorphic rock,
which is formed when chalk or limestone is
recrystallised under conditions of high temperature and
pressure. Large deposits of marble are found in North
America and in Europe; e.g., in Carrara, Italy, the home
of the pure white “statuario” from which Michelangelo
created his sculptures.
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Calcium carbonate, as it is used for industrial purposes, is extracted by mining
or quarrying. Pure calcium carbonate can be produced from marble, or it can be
prepared by passing carbon dioxide into a solution of calcium hydroxide. In the
later case calcium carbonate is derived from the mixture, forming a grade of
product called “precipitated calcium carbonate,” or PCC.
PCC has a very fine and
controlled particle size, on the order of 2 microns in diameter, particularly
useful in production of paper. The other primary type of industrial product is
“ground calcium carbonate,” or GCC.
GCC, as the name implies, involves crushing
and processing limestone to create a powdery-like form graded by size and other
properties for many different industrial and pharmaceutical applications. |
A study of calcium carbonate provides important lessons about the history of the
earth, since chalk, limestone and marble trace their origin to shallow water.
Thus, observation that large amounts of chalk deposits of the same age are found
on many continents led to the discovery that there existed a period in which
there was shallow water world-wide where shelled organisms thrived. Some offer
this as proof for the Biblical flood. Nature returns the favor as calcium
carbonate solutions from current deposits provide living organisms today with
the material they need to grow their protective shells and skeletons. Eggshells,
for example, are composed of approximately 95% calcium carbonate.
Calcium carbonate causes a unique reaction with acids. Upon contact with an acid
– no matter the strength – it produces carbon dioxide. This provides geologists
with a reliable test to identify calcium carbonate. This same phenomenon is
important to the formation of caves. Acidic rain water runs off and goes
underground where it dissolves the calcium carbonate limestone. The calcium
carbonate water runs down and eventually reaches an air-filled cavity
underground where the carbon dioxide can be released. When it is released, the
calcium carbonate crystallizes again. Stalactite and stalagmite formations are
created when water containing calcium carbonate drips, leaving some mineral at
the source of the drip
at the roof of the cave and some where it falls. This is an extremely long
process, and often takes place over many thousands of years.
As interesting as calcium carbonate may be in nature, its impact and value to
our everyday life are truly extraordinary. |
Paper, Plastics,
Paints, and Coatings |
Calcium
carbonate is the most widely used mineral in the paper, plastics, paints and
coatings industries both as a filler – and due to its special white color – as a
coating pigment. In the paper industry it is valued worldwide for its high
brightness and light scattering characteristics, and is used as an inexpensive
filler to make bright opaque paper. Filler is used at the wet-end of paper
making machines, and calcium carbonate filler allows for the paper to be bright
and smooth. As an extender, calcium carbonate can represent as much as 30% by
weight in paints. Calcium carbonate also is used widely as a filler in
adhesives, and sealants. |
Personal
Health and Food Production
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Calcium
carbonate is used widely as an effective dietary calcium supplement, antacid,
phosphate binder, or base material for medicinal tablets. It also is found on
many grocery store shelves in products such as baking powder, toothpaste,
dry-mix dessert mixes, dough, and wine. Calcium carbonate is the active
ingredient in agricultural lime, and is used in animal feed. Calcium carbonate
also benefits the environment through water and waste treatment. |
Building
Materials and ConstructionCalcium
carbonate is critical to the construction industry, both as a building material
in its own right (e.g. marble), and as an ingredient of cement. It contributes
to the making of mortar used in bonding bricks, concrete blocks, stones, roofing
shingles, rubber compounds, and tiles. Calcium carbonate decomposes to form
carbon dioxide and lime, an important material in making steel, glass, and
paper. Because of its antacid properties, calcium carbonate is used in
industrial settings to neutralize acidic conditions in both soil and water. |
Calcium carbonate crystals are referred to as calcite. The calcite crystal
generally is considered a rhombohedron because of its cleavage properties.
Cleavage is what causes crystals to angle where the bonding forces are weak and
are apt to break into planes. Calcite is unique in that its cleavage takes three
distinct directions. There are more than 300 forms of calcite crystals. Calcite
crystals also come in many different colors, but usually are white or
transparent. Another important property of the calcite crystal is its property
of double refraction. Double refraction occurs when a ray of light travels
through a medium and is split into two different beams, one traveling slowly,
one traveling fast. The two different beams are bent at two different angles of
refraction. As a result of this property a person looking through calcite sees
two images. This property of double refraction is a feature valuable to a number
of optical applications. |
Ground Calcium Carbonate powder
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request
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product |
Calcium Carbonate |
grade |
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Berkeley International |
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Berkeley International |
F-13A-02 Metropolitan Square |
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Newcastle on Tyne |
Damansara Perdana |
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NE3 |
47820 Petaling Jaya |
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Phone +44 1916451227 |
Malaysia |
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alex@berkeleyinternational.net |
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john@berkeleyinternational.net |
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suzanne@berkeleyinternational.net |
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Phone +603 7731 2242 |
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